yes, I had that too and was buying the grade 2s in the GTM. But then once I started seeing the grade 2s on planet, I stopped seeing the grade 1s as well, and now a couple planets later I'm noticing that the 100-something grade 1s I saved up are now gone, and I can't craft things that require those, which seems to be most things. But it could be entirely possible that I'm mistaken.
I also did not know that you could redo the early missions, I just show missions for grade 2 metals and compounds, so I've got a decent amount of terenthium which doesn't do much without the desh needed also.