I would say in terms of Sith:
1. Abeloth (Not sure if she counts as Sith, but oh well)
2. Darth Bane
3. Darth Revan
4. Darth Caedus
5. Naga Sadow
6. Darth Sidious
7. Darth Sion
8. Sarasu Taalon
9. Garen Malek
10. Darth Wyyrlok III
Jedi are as follows in my view:
1. Luke Skywalker
2. Satele Shan
3. Cade Skywalker
4. Yoda
5. Kol Skywalker
6. Ben Skywalker
7. Anakin Skywalker
8. Jaina Solo
9. Leia Organa Solo
10. Kyle Katarn