Sith Juggernaut- Immortal is pretty enjoyable if you're really going for a Darth Vader-type feel, it's pretty satisfying to Force Choke someone and then leave them to that while you Ravage the poor unfortunate's equally-unfortunate friend.
Also fond of Sith Assassin/Scoundrel, especially if you've played through a couple times and don't want to engage EVERY single enemy in your path, having stealth's a good option to get through it, and when you do choose to fight it's fun to shoot some unsuspecting NPC in the back of the head with a shotgun, or lift them into the air and stab them.
Still, Sith Sorcerer is my favorite, for reasons covered previously: Lightning is flashy and cool and fits with the rest of the story cinematics.