I can't speak to any other professions, but for armstech/scavenging, starting at rank 4 (where the 3rd tier of white vendor item shows up) those missions will give you MUCH better yield for the price than purchasing them off the vendor. If you're looking to make money off the profession, or just save some credits while leveling, you should take advantage of these missions while they're available, especially in bountiful or rich form. If it's actually terribly inconvenient, here's a little trick you can use. Every time you learn one of the blue/purple missions from slicing, it will completely repopulate your mission list. And there's almost always a few of these missions for sale on the GTN for cheap. So if you're really in that bad need of raw materials, you can always pick up a bioanalysis mission, learn it, then check your mission list again to see what popped up. If you get a new mission you want, great. The mission you just learned will wait for you as long as you need. If not, at least you'll get a good chunck of materials for your trouble.